Choose an application

• Reference Manager
• EndNote
• RefWorks (Direct export to RefWorks)

Non-covalent interactions in coordination and organometallic compounds (hydrogen, halogen, chalcogen, pnictogen, tetrel, and semi-coordination bonds; agosic and anagosic interactions; stacking, anion-/cation-π interactions; metallophilic interactions, etc.) are topical in modern chemistry, materials science, crystal engineering, and related fields of knowledge. Both experimental and theoretical methods are widely used for investigations of the nature and various properties of such weak contacts in gas, liquid, and solid states. Non-covalent interactions could be the driving force to design smart materials with valuable redox, electronic, mechanical, magnetic, and optical properties, which is promising for the manufacture of LEDs, photovoltaic cells of solar power plants, porous structures, sensors, battery cells, and liquid crystals.This Special Issue highlights and presents an overview of modern trends in non-covalent interactions in coordination and organometallic compounds, and bringing various different types to the attention of the scientific community.

Technology: general issues --- non-covalent interactions --- crystal engineering --- organometallic compounds --- coordination compounds --- crystalline materials --- supramolecular systems --- hydrazones --- sonochemical-based synthesis --- single-crystal analysis --- non-covalent interaction --- Hirshfeld surface study --- silver phosphine --- pyrazole --- luminescence --- TD-DFT --- IsoStar --- Cambridge Structural Database --- Protein Data Bank --- noncovalent interactions --- crystal structure --- coordination polymer --- sonochemical route --- X-ray crystallography --- nanorods --- Pb(II) --- ultrasonic irradiation --- nano metal oxide

Choose an application

• Reference Manager
• EndNote
• RefWorks (Direct export to RefWorks)

This book is about supramolecular gold chemistry. This book provides a unique international forum aimed at covering a broad description of results involving the supramolecular chemistry of gold with a special focus on the gold–sulfur interface leading to hybrid materials ranging from gold–thiolate complexes to thiolate-protected gold nanoclusters and gold–thiolate supramolecular assemblies or nanoparticles. The role of thiolates on the structure and optical features of gold nanohybrid systems (ranging from plasmonic gold nanoparticles and fluorescent gold nanoclusters to self-assembled Au-containing thiolated coordination polymers) is highlighted in the 12 papers presented in this book.

Technology: general issues --- alloy --- metal exchange --- atomically precise --- gold nanoclusters --- thiolate --- catenane --- ion mobility --- DFT calculations --- gold nanocluster --- cross-coupling --- Ullmann hetero-coupling --- Sonogashira coupling --- Suzuki coupling --- A3−coupling --- catalytic mechanism --- ligand removal --- gold nanomaterials --- electron dynamics --- phonon dynamics --- optical properties --- Au70S20(PPh3)12 cluster --- superatom network model --- electronic structure --- geometric structure --- gold nanoparticles --- graphene oxide --- laser ablation --- Au-GO nano-hybrid --- coordination polymer structure --- amino acids --- template-assisted synthesis --- fluorescence --- Au(I)-thiolate --- gold nanohybrid materials --- 3-MBA/Au MPCs --- TEA-HFIP --- ESI-MS --- HPLC-MS --- bidentate binding --- gold thiolate --- coordination polymer --- lamellar structure --- luminescence --- polymer composite --- gold --- cluster --- catalyst --- hydrogen evolution reaction --- oxygen evolution reaction --- oxygen reduction reaction --- water splitting --- fuel cells --- ligand-protected --- photoluminescence mechanism --- metal nanoclusters --- quantum confinement effect --- ligand effect --- p band intermediate state (PBIS) --- interface state --- nanocatalysis --- 6-aza-2-thio-thymine --- protein --- n/a

Choose an application

• Reference Manager
• EndNote
• RefWorks (Direct export to RefWorks)

This book is about supramolecular gold chemistry. This book provides a unique international forum aimed at covering a broad description of results involving the supramolecular chemistry of gold with a special focus on the gold–sulfur interface leading to hybrid materials ranging from gold–thiolate complexes to thiolate-protected gold nanoclusters and gold–thiolate supramolecular assemblies or nanoparticles. The role of thiolates on the structure and optical features of gold nanohybrid systems (ranging from plasmonic gold nanoparticles and fluorescent gold nanoclusters to self-assembled Au-containing thiolated coordination polymers) is highlighted in the 12 papers presented in this book.

alloy --- metal exchange --- atomically precise --- gold nanoclusters --- thiolate --- catenane --- ion mobility --- DFT calculations --- gold nanocluster --- cross-coupling --- Ullmann hetero-coupling --- Sonogashira coupling --- Suzuki coupling --- A3−coupling --- catalytic mechanism --- ligand removal --- gold nanomaterials --- electron dynamics --- phonon dynamics --- optical properties --- Au70S20(PPh3)12 cluster --- superatom network model --- electronic structure --- geometric structure --- gold nanoparticles --- graphene oxide --- laser ablation --- Au-GO nano-hybrid --- coordination polymer structure --- amino acids --- template-assisted synthesis --- fluorescence --- Au(I)-thiolate --- gold nanohybrid materials --- 3-MBA/Au MPCs --- TEA-HFIP --- ESI-MS --- HPLC-MS --- bidentate binding --- gold thiolate --- coordination polymer --- lamellar structure --- luminescence --- polymer composite --- gold --- cluster --- catalyst --- hydrogen evolution reaction --- oxygen evolution reaction --- oxygen reduction reaction --- water splitting --- fuel cells --- ligand-protected --- photoluminescence mechanism --- metal nanoclusters --- quantum confinement effect --- ligand effect --- p band intermediate state (PBIS) --- interface state --- nanocatalysis --- 6-aza-2-thio-thymine --- protein --- n/a

Choose an application

• Reference Manager
• EndNote
• RefWorks (Direct export to RefWorks)

The crystal chemistry of spin crossover (SCO) behavior in coordination compounds can potentially be in association with smart materials—promising materials for applications as components of memory devices, displays, sensors and mechanical devices and, especially, actuators, such as artificial muscles. This Special Issue is devoted to various aspects of SCO and related research, comprising 18 interesting original papers on valuable and important SCO topics. Significant and fundamental scientific attention has been focused on the SCO phenomena in a wide research range of fields of fundamental chemical and physical and related sciences, containing the interdisciplinary regions of chemical and physical sciences related to the SCO phenomena. Coordination materials with bistable systems between the LS and the HS states are usually triggered by external stimuli, such as temperature, light, pressure, guest molecule inclusion, soft X-ray, and nuclear decay. Since the first Hofmann-like spin crossover (SCO) behavior in {Fe(py)2[Ni(CN)4]}n (py = pyridine) was demonstrated, this crystal chemistry motif has been frequently used to design Fe(II) SCO materials to enable determination of the correlations between structural features and magnetic properties.

n/a --- hexadentate ligand --- X-ray diffraction --- structural disorder --- lattice energy --- 2-bis(4-pyridyl)ethane --- thermal hysteresis --- optical conductivity spectrum --- spin-state crossover --- solvate --- single crystal --- spin-crossover transition --- spin-crossover --- cobalt oxide --- amorphous --- metal dithiolene complexes --- qsal ligand --- impurity effect --- 3-triazole --- intermolecular interactions --- spin crossover --- hydrogen bonding --- 1 --- 2 --- optical microscopy --- supramolecular coordination polymer --- paramagnetic ligand --- magnetic susceptibility --- high spin --- [Fe(III)(3-OMesal2-trien)]+ --- aminoxyl --- cobalt(II) ion --- mosaicity --- Fe(III) coordination complexes --- nitroxides --- C–H···? interactions --- Fe(II) --- dithiooxalato ligand --- dinuclear triple helicate --- coordination polymers --- magnetization --- spiral structure --- magnetostructural correlations --- charge-transfer phase transition --- structure phase transition --- magnetic properties --- spin polaron --- substitution of 3d transition metal ion --- iron(II) complexes --- X-ray absorption spectroscopy --- coordination complexes --- crystal engineering --- fatigability --- soft X-ray induced excited spin state trapping --- spin transition --- dipyridyl-N-alkylamine ligands --- coordination polymer --- iron (II) --- iron mixed-valence complex --- chiral propeller structure --- spin cross-over (SCO) --- EPR spectroscopy --- Cu(II) complexes --- solvent effects --- ferromagnetism --- SQUID --- LIESST effect --- low spin (LS) --- 57Fe Mössbauer spectroscopy --- dielectric response --- iron(II) --- hetero metal complex --- atropisomerism --- switch --- Schiff base --- counter-anion --- DFT calculation --- Fe(III) complex --- Fe(II) complex --- high spin (HS) --- reaction diffusion --- thermochromism --- supramolecular isomerism --- phase transition --- magnetic transition --- mononuclear --- [Au(dmit)2]? --- UV-Vis spectroscopy --- phase transitions --- ?-? interactions --- [Au(dddt)2]? --- crystal structure --- linear pentadentate ligand --- ion-pair crystals --- C-H···? interactions --- 57Fe Mössbauer spectroscopy

Choose an application

• Reference Manager
• EndNote
• RefWorks (Direct export to RefWorks)

This book is a printed edition of the Special Issue Crystal Chemistry of Zinc, Cadmium and Mercury that was published in Crystals

hydroxyl group --- bis(1 --- quinaldinic acid --- solidification --- xanthate --- wurtzite --- mechanical --- EBSD --- oxo-centred polyhedra --- coordination polymer --- precipitation --- 5-thiophenedicarboxylic acid --- defects in semiconductors --- zinc(II) complexes --- precursor --- nanometer zinc oxide --- zinc --- thermal analysis --- transmission electron microscopy (TEM) --- crystal chemistry --- pyridine --- dithiocarbamate --- high magnetic field --- index of X-ray powder diffraction data --- 1 --- hydrogen bonding --- 2 --- luminescence --- cadmium --- interface structure --- 3-bis(1 --- mercury --- aqueous solution method --- crystallography --- growth mechanism --- PL spectra --- phonon dispersion --- coordination polymers --- 4-triazol-1-yl)propane --- CdZnTe --- oxochromates(VI) --- Ni3Sn structure type --- structural chemistry --- dithiophosphates --- traveling heater method --- ZnO nanorod arrays --- copper amalgams --- dental amalgams --- unusual coordination modes --- CdS --- zinc-rich crystal --- 4-triazol-1-yl)methane --- elastic --- crystal structure --- phonon --- bitopic ligand --- room-temperature solid state reaction --- zinc complex --- characterization --- crystal engineering --- ZnS --- hydrogen bond